Poly[diacetonitrile[μ3-difluoro(oxalato)borato]sodium]
نویسندگان
چکیده
The title compound, [Na(C(2)BF(2)O(4))(CH(3)CN)(2)](n), forms infinite two-dimensional layers running parallel to (010). The layers lie across crystallographic mirror planes at y = 1/4 and 3/4. The Na, B and two F atoms reside on these mirror planes. The Na(+) cations are six-coordinate. Two equatorial coordination positions are occupied by acetonitrile mol-ecules. The other two equatorial coordination sites are occupied by the chelating O atoms from the difluoro-(oxalato)borate anion (DFOB(-)). The axial coordination sites are occupied by two F atoms from two different DFOB(-) anions.
منابع مشابه
Poly[[di-μ3-nicotinato-μ3-oxalato-samarium(III)silver(I)] dihydrate]. Corrigendum
The title of the paper by Zhu, Zhao & Yu [Acta Cryst. (2009), E65, m1105] is corrected.[This corrects the article DOI: 10.1107/S1600536809032115.].
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011